Synthesis and Characterization of Neutral Ru(III) Complexes Containing Schiff Bases and N-donor Heterocyclic Ligands

Authors

  • Sabina Begić Author
  • Nevzeta Ljubijankić Author

Abstract

Two new neutral complex compounds of Ru(III) with Schiff bases and N-donor heterocyclic ligands have been synthesized. Based on MALDI TOF/TOF mass spectra, CHN elemental analysis, infrared and electronic spectra the synthesized compounds were formulated as [RuCl(N-Ph-5-X-salim)2B], where X = Cl for B = Py and X = Br for B = Pym. In the octahedral environment of Ru(III), bidentate Schiff bases acts as anionic ligand where coordination occurs via deprotonated phenolic oxygen and azomethine nitrogen atom. Coordination of monodentate N-donor heterocyclic ligands occurs through free electronic pair on the nitrogen atom.

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Published

2016-12-01

Issue

Vol. 47 (2016): Bulletin of the Chemists and Technologists of Bosnia and Herzegovina

Section

Original Scientific Article

How to Cite

Begić, S. and Ljubijankić, N. (2016) “Synthesis and Characterization of Neutral Ru(III) Complexes Containing Schiff Bases and N-donor Heterocyclic Ligands”, Bulletin of Chemists and Technologists of Bosnia and Herzegovina, 47, pp. 27–32. Available at: https://glashem.pmf.unsa.ba/index.php/bctbh/article/view/178 (Accessed: 28 July 2026).